Formulae of Ions
The charge of an ion is given in superscript in its formula whereas the numbers of each type of atom are subscript. For example SO42- consists of 1 sulphur atom, 4 oxygen atoms and has a 2- charge.
Simple positive ions are formed by hydrogen and the metals. A positive ion (cation) made of one atom has the same name as its element.
For groups 1-3, the amount of positve charge is the same as the group number. A transition metal often can form several different ions and the amount of positive charge on its ion is given in roman numerals in the compound's name: for example iron (III) chloride contains Fe3+ ions whereas iron (II) chloride contains Fe2+ ions.
| Cation name | Periodic table group of element from which cation is made | Cation symbol | 
|---|---|---|
| Hydrogen | H+ | |
| Lithium | 1 | Li+ | 
| Sodium | 1 | Na+ | 
| Potassium | 1 | K+ | 
| Magnesium | 2 | Mg2+ | 
| Calcium | 2 | Ca2+ | 
| Aluminium | 3 | Al3+ | 
| Tin(II) and tin(IV) | 4 | Sn2+ and Sn4+ | 
| Lead(II) and lead(IV) | 4 | Pb2+ and Pb4+ | 
| Iron(II) and iron(III) | transition | Fe2+ and Fe3+ | 
| Copper(I) and copper(II) Copper(II) is more commonly encountered than copper(I). | transition | Cu+ and Cu2+ | 
| Zinc | Zn2+ | |
| Silver | transition | Ag+ | 
| Ammonium | NH4+ | 
Simple negaive ions (anions) are formed from non-metals. The name of a simple anion starts with the first part of the element's name and ends with -ide. The amount of charge = (group number - 8).
| Name of element from which anion is formed. | Periodic table group of element | Anion name | Anion symbol | 
|---|---|---|---|
| Oxygen | 6 | Oxide | O2- | 
| Sulfur | 6 | Sulfide | S2- | 
| Fluorine | 7 | Fluoride | F- | 
| Chlorine | 7 | Chloride | Cl- | 
| Bromine | 7 | Bromide | Br- | 
| Iodine | 7 | Iodide | I- | 
| Nitrogen | 5 | Nitride | N3- | 
| Phosphorus | 5 | Phosphide | P3- | 
These are negative ions consisting of several atoms. All the examples below contain oxygen and another element's atoms. The presence of oxygen atoms is indicated by the endings -ite or -ate. There is more oxygen in an '-ate' than in the corresponding '-ite'. When a negative ion is combined with a H+, the compound is an acid. The formulas of these ions are not predictable from the periodic table and they need to be learnt.
| Molecular anion name | Formula | Name and formula of the acid containing the anion | 
|---|---|---|
| Carbonate | CO32- | Carbonic acid, H2CO3 (unstable, decomposes into H2O and CO2) | 
| Hydrogencarbonate | HCO3- | Carbonic acid, H2CO3 (unstable, decomposes into H2O and CO2) | 
| Nitrate | NO3- | Nitric acid, HNO3 | 
| Nitrite | NO2- | Nitrous acid, HNO2 | 
| Sulfate | SO42- | Sulfuric acid, H2SO4 | 
| Hydrogensulfate | HSO4- | Sulfuric acid, H2SO4 | 
| Sulfite | SO32- | Sulfurous acid, H2SO3 | 
| Phosphate | PO43- | Phosphoric acid, H3PO4 | 
| Hydroxide | OH- | (Water, H2O) | 
| Ethanoate | CH3COO- | Ethanoic acid, CH3COOH | 
| Thiosulfate | S2O32- | (unstable) |