Formulae of Ions
The charge of an ion is given in superscript in its formula whereas the numbers of each type of atom are subscript. For example SO42- consists of 1 sulphur atom, 4 oxygen atoms and has a 2- charge.
Simple positive ions are formed by hydrogen and the metals. A positive ion (cation) made of one atom has the same name as its element.
For groups 1-3, the amount of positve charge is the same as the group number. A transition metal often can form several different ions and the amount of positive charge on its ion is given in roman numerals in the compound's name: for example iron (III) chloride contains Fe3+ ions whereas iron (II) chloride contains Fe2+ ions.
Cation name | Periodic table group of element from which cation is made | Cation symbol |
---|---|---|
Hydrogen | H+ | |
Lithium | 1 | Li+ |
Sodium | 1 | Na+ |
Potassium | 1 | K+ |
Magnesium | 2 | Mg2+ |
Calcium | 2 | Ca2+ |
Aluminium | 3 | Al3+ |
Tin(II) and tin(IV) | 4 | Sn2+ and Sn4+ |
Lead(II) and lead(IV) | 4 | Pb2+ and Pb4+ |
Iron(II) and iron(III) | transition | Fe2+ and Fe3+ |
Copper(I) and copper(II) Copper(II) is more commonly encountered than copper(I). |
transition | Cu+ and Cu2+ |
Zinc | Zn2+ | |
Silver | transition | Ag+ |
Ammonium | NH4+ |
Simple negaive ions (anions) are formed from non-metals. The name of a simple anion starts with the first part of the element's name and ends with -ide. The amount of charge = (group number - 8).
Name of element from which anion is formed. | Periodic table group of element | Anion name | Anion symbol |
---|---|---|---|
Oxygen | 6 | Oxide | O2- |
Sulfur | 6 | Sulfide | S2- |
Fluorine | 7 | Fluoride | F- |
Chlorine | 7 | Chloride | Cl- |
Bromine | 7 | Bromide | Br- |
Iodine | 7 | Iodide | I- |
Nitrogen | 5 | Nitride | N3- |
Phosphorus | 5 | Phosphide | P3- |
These are negative ions consisting of several atoms. All the examples below contain oxygen and another element's atoms. The presence of oxygen atoms is indicated by the endings -ite or -ate. There is more oxygen in an '-ate' than in the corresponding '-ite'. When a negative ion is combined with a H+, the compound is an acid. The formulas of these ions are not predictable from the periodic table and they need to be learnt.
Molecular anion name | Formula | Name and formula of the acid containing the anion |
---|---|---|
Carbonate | CO32- | Carbonic acid, H2CO3 (unstable, decomposes into H2O and CO2) |
Hydrogencarbonate | HCO3- | Carbonic acid, H2CO3 (unstable, decomposes into H2O and CO2) |
Nitrate | NO3- | Nitric acid, HNO3 |
Nitrite | NO2- | Nitrous acid, HNO2 |
Sulfate | SO42- | Sulfuric acid, H2SO4 |
Hydrogensulfate | HSO4- | Sulfuric acid, H2SO4 |
Sulfite | SO32- | Sulfurous acid, H2SO3 |
Phosphate | PO43- | Phosphoric acid, H3PO4 |
Hydroxide | OH- | (Water, H2O) |
Ethanoate | CH3COO- | Ethanoic acid, CH3COOH |
Thiosulfate | S2O32- | (unstable) |